Visible light-promoted alkylation of imines using potassium organotrifluoroborates

被引：0
|
作者：
Davis P. Plasko
Christopher J. Jordan
Brittney E. Ciesa
Madison A. Merrill
James M. Hanna
机构：
[1] Winthrop University,Department of Chemistry, Physics, and Geology
来源：
Photochemical & Photobiological Sciences | 2018年 / 17卷
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学科分类号：
摘要：
A mild, redox-neutral, alkylation of imines with potassium alkyl-trifluoroborates is described. The reaction proceeds under photo-redox conditions at ~30 °C with primary, secondary, and tertiary alkyltrifluoroborates, leading to alkylation products in moderate to good yield in most cases. Aryl-, vinyl-, and cyclopropyltrifluoroborates failed to react under the reported conditions.
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页码：534 / 538
页数：4
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