Polymerization of methyl methacrylate using the NiX2(PPh3)2/Zn catalytic system

被引：0
作者：
I. S. Il’ichev
N. B. Valetova
M. V. Moskalev
D. F. Grishin
机构：
[1] Lobachevsky State University of Nizhni Novgorod,Research Institute for Chemistry
来源：
Kinetics and Catalysis | 2008年 / 49卷
关键词：
PMMA; Atom Transfer Radical Polymerization; Atom Transfer Radical Polymerization; Methyl Methacrylate; Nickel Complex;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The NiBr2(PPh3)2/Zn catalytic system in combination with the PhI initiator ensures methyl methacrylate polymerization in a wide temperature range. The polymer yield is determined by the ligand environment of the nickel atom, the reaction temperature, and the ratio of the components of the catalytic system. An analysis of the macrokinetic relationships and of the molecular-weight characteristics of the products indicates that polymerization occurs in a controlled regime.
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页码：531 / 536
页数：5
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