Oxidation of γ-stannyl sulfides by monochloramine CB and hydrogen peroxide

被引：0
作者：
V. I. Shcherbakov
N. E. Stolyarova
Yu. A. Kurskii
机构：
[1] Russian Academy of Sciences,G. A. Razuvaev Institute of Organometallic Chemistry
来源：
Russian Chemical Bulletin | 1997年 / 46卷
关键词：
pentyl 3-(trimetylstannyl)propyl sulfide; oxidation; γ-trimethylstannyl sulfimide; γ-trimethylstannyl sulfoximide; γ-trimethylstannyl sulfoxide; γ-trimethylstannyl sulfone;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The first γ-trimethylstannyl sulfimide, Me3Sn(CH2)3S(=NSO2Ar)C5H11-n, was synthesized by oxidative imination of Me3Sn(CH2)3SC5H11-n with ArSO2(Na)Cl (Ar=C6H4Cl-4). Oxidation of γ-trimethylstannyl sulfimide by an alkaline solution of H2O2 gave γ-trimethylstannyl sulfoximide, Me3Sn(CH2)3S(O)(=NSO2Ar)C5H11-n, and γ-trimethylstannyl sulfone, Me3Sn(CH2)3SO2C5H11-n, the latter compound resulting from hydrolysis of the arylsulfimide group. Oxidation of stannyl sulfide by hydrogen peroxide yielded γ-trimethylstannyl sulfoxide, Me3Sn(CH2)3S(O)C5H11-n (under mild conditions) or γ-trimethylstannyl sulfone (under more severe conditions).
引用
收藏
页码：358 / 361
页数：3
相关论文
共 26 条
[1]  
Shcherbakov V. I.(1993)undefined Metallorg. Khim. 6 330-330
[2]  
Stolyarova N. E.(1977)undefined Chem. Rev. 77 409-409
[3]  
Gilchrist T. L.(1990)undefined Usp. Khim. 59 1409-1409
[4]  
Moody C.(1990)undefined Inorg. Chim. Acta. 172 225-225
[5]  
Koval I. V.(1983)undefined J. Organomet. Chem. 224 225-225
[6]  
Cox P. J.(1981)undefined J. Organomet. Chem. 205 C24-C24
[7]  
Doidge-Harrison M. S. W.(1971)undefined J. Organomet. Chem. 26 215-215
[8]  
Nowell I. W.(1970)undefined Bull. Chem. Soc. Jpn. 43 2153-2153
[9]  
Howie R. A.(1991)undefined Metalloorg. Khim. 4 1350-1350
[10]  
Randall A. P.(1961)undefined Z. Anal. Chem. 187 28-28
123