Molecular Recognition and Interfacial Catalysis at Liquid-Liquid Interfaces

被引：0
作者：
Alexander G. Volkov
机构：
[1] University of California at Los Angeles,Department of Civil and Environmental Engineering, 5732F Boelter Hall
来源：
Analytical Sciences | 1998年 / 14卷
关键词：
Oil/water interface; Kelvin probe; vibrating condenser; molecular recognition; interfacial catalysis; cytochrome oxidase; porphyrins;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The interface between two immiscible liquids with immobilized metalloporphyrins, enzymes and submitochondrial particles can serve as the simplest model of biological membrane convenient for the investigation of redox reaction accompanied by spatial separation of charges. In this mini review, we have described the vectorial charge transfer and molecular recognition at liquid/liquid interfaces. The structure of liquid interfaces, donor-acceptor interactions in the electrical double layer, hydrogen and specific bounding between molecules play the dominant role in molecular recognition and interfacial catalysis.
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页码：19 / 25
页数：6
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