Control of the sign of exchange interactions in solvent-separated radical ion pairs

被引：0
|
作者：
S. Tero-Kubota
K. Zikihara
T. Yago
Y. Kobori
K. Akiyama
机构：
[1] Tohoku University,Institute of Multidisciplinary Research for Advanced Materials
[2] University of Chicago,Department of Chemistry
来源：
Applied Magnetic Resonance | 2004年 / 26卷
关键词：
DABCO; Reorganization Energy; Saturated Calomel Reference Electrode; Cyclic Voltammetry Measurement; Hyperfine Coupling Constant;
D O I：
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学科分类号：
摘要：
The chemically induced dynamic electron polarization spectra generated by the laser photolysis of several donor-acceptor systems have been studied to verify the solvent effects on the exchange interaction in solvent-separated radical ion pairs. It has been shown that the sign of the exchange interaction depends on the polarity of solvents. The individual reorganization energies have been determined for several solvent-separated radical ion pair systems.
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页码：145 / 154
页数：9
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