Design and synthesis by redox polymerization of a bio-based carboxylic elastomer for green tire

被引：0
作者：
Xinxin Zhou
Runguo Wang
Weiwei Lei
He Qiao
Haoling Ji
Liqun Zhang
Kuo-Chih Hua
Joseph Kulig
机构：
[1] Beijing University of Chemical Technology,State Key Laboratory of Organic
[2] Beijing University of Chemical Technology,Inorganic Composites
[3] Beijing University of Chemical Technology,Key Laboratory of Beijing City for Preparation and Processing of Novel Polymer Materials
[4] Goodyear Tire & Rubber Company,Beijing Laboratory of Biomedical Materials
[5] D/460F,Goodyear Innovation Center
来源：
Science China Chemistry | 2015年 / 58卷
关键词：
carboxylic rubber; bio-based elastomer; synthesis; redox polymerozation; green tire;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Poly(dibutyl itaconate-co-isoprene-co-methacrylic acid) (PDIM) elastomer was designed and synthesized by redox emulsion polymerization under mild conditions. PDIM has high molecular weight, relatively high yield, and low glass transition temperature (Tg). The structure of PDIM was determined by FTIR and NMR, and the carboxyl content was obtained by titration in a non-proton solvent. Tensile strength and elongation at break increased with increasing carboxyl content. In addition, the interaction between PDIM and silica was elucidated by rubber process analyzer (RPA) and TEM, and the results showed that the silica-PDIM interaction was strong, but the silica-silica interaction was weak.
引用
收藏
页码：1561 / 1569
页数：8
相关论文
共 114 条
[1]  
Hall DE(2001)Fundamentals of rolling resistance Rubber Chem Technol 74 525-539
[2]  
Moreland JC(2011)Investigations on rolling resistance of nanocomposite based passenger car radial tyre tread compounds using simulation technique Tire Sci Technol 39 210-222
[3]  
Ghosh S(1987)Silanes in tire compounding after ten years—a review Tire Sci Technol 15 276-294
[4]  
Sengupta RA(2006)Nanoclay reinforced bio-based elastomers: synthesis and characterization Polymer 47 8106-8115
[5]  
Heinrich G(2014)Trends in green tire manufacturing Rubber World 249 32-38
[6]  
Wolff S(2014)Silica-reinforced tire tread compounds compatibilized by using epoxidized natural rubber Eur Polym J 51 69-79
[7]  
Zhu L(2010)Studies on novel dual filler based epoxidized natural rubber nanocomposite Polym Compos 31 835-846
[8]  
Wool RP(2007)Natural rubber and NR-based polymers: renewable materials with unique properties Transport 5 8-118
[9]  
Job KA(2012)Tough bio-based elastomer nanocomposites with high performance for engineering applications Adv Eng Mater 14 112-6839
[10]  
Sengloyluan K(2012)Design and preparation of a novel cross-linkable, high molecular weight, and bio-based elastomer by emulsion polymerization Macromolecules 45 6830-9019
12345678910