Thermodynamic Properties of FeNb2O6 and FeTa2O6

被引:0
作者
A. N. Mansurova
V. M. Chumarev
R. I. Gulyaeva
机构
[1] Russian Academy of Sciences,Institute of Metallurgy, Ural Branch
来源
Inorganic Materials | 2018年 / 54卷
关键词
iron niobate; iron tantalate; thermodynamic properties; entropy; enthalpy; heat capacity; melting point;
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摘要
Empirical calculational approaches have been used to evaluate the enthalpy, entropy, heat capacity, and melting point of iron(II) niobate and iron(II) tantalate and the coefficients A, B, and C in an equation for the temperature dependence of their heat capacity. The melting point of FeTa2O6 has been experimentally determined to be 1891 ± 5 K. The calculated heat capacity (C°p (298.15 K)) of iron tantalate and the Gibbs energies of formation of FeN2O6 and FeTa2O6 have been compared to previously reported data.
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页码:700 / 705
页数:5
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