Molecular mechanism of the spontaneous segregation of enantiomers in liquid nanoblobs

被引：0
|
作者：
D. V. Zlenko
M. A. Tregubova
S. V. Stovbun
机构：
[1] Lomonosov Moscow State University,Semenov Institute of Chemical Physics
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Physical Chemistry B | 2017年 / 11卷
关键词：
chirality; spontaneous segregation; molecular modeling; enantiomer excess;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
At present, the problem of spontaneous segregation has no satisfactory theoretical description. The main difficulty is a very low probability of the spontaneous formation of a chirally pure nucleus in a racemic mixture if the enantioselectivity energy is below (10–12)kT, which does not correspond to reality. In this paper, we propose a mechanism of the enhancement of enantioselectivity in the chiral phase nucleus, which circumvents the problem of the low probability of its formation.
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收藏
页码：343 / 347
页数：4
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