Binuclear cluster complexes of molybdenum containing 2,2′-bipyridine and 1,10-phenanthroline: Synthesis and structure

被引：0

作者：

A. L. Gushchin

Yu. L. Laricheva

N. I. Alferova

A. V. Virovets

M. N. Sokolov

机构：

[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division

[2] Novosibirsk State University,undefined

来源：

Journal of Structural Chemistry | 2013年 / 54卷

关键词：

binuclear clusters; molybdenum; polypyridine ligands; crystal structure; IR spectra;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

By the interaction between (Et4N)2[Mo2O2S8] and I2 in DMF with a subsequent addition of 2,2′-bipyridine or 1,10-phenanthroline, new binuclear complexes [Mo2O2S2I2(bipy)2] (1) and [Mo2O2S2I2(phen)2] (2) are obtained. The structure of [Mo2O2S2I2(bipy)2] is determined using single crystal X-ray diffraction. The compounds are characterized by elemental analysis and IR spectra. The [MoO(S2)2(bipy)] complex as a product of oxidative destruction of 1 is isolated and characterized.

引用

页码：752 / 758

页数：6

共 50 条

[1] Binuclear cluster complexes of molybdenum containing 2,2′-bipyridine and 1,10-phenanthroline: Synthesis and structure
Gushchin, A. L.
Laricheva, Yu. L.
Alferova, N. I.
Virovets, A. V.
Sokolov, M. N.
JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 54 (04) : 752 - 758
[2] Cadmium(II) diallyldithiocarbamato complexes with 2,2'-bipyridine and 1,10-phenanthroline: spectroscopic and crystal structure analysis
Ali, B. F.
Al-Far, R.
Zaghal, M. H.
Judeh, Z.
Haddad, S. F.
JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (12) : 2028 - 2036
[3] Coordination structure and intermolecular interactions in copper(II) acetate complexes with 1,10-phenanthroline and 2,2′-bipyridine
Guimaraes, Samuel P.
Dos Santos, Leonardo H. R.
Rodrigues, Bernardo L.
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2024, 80 : 505 - +
[4] Synthesis, characterization and structure assessment of mononuclear and binuclear low-spin manganese(II) complexes derived from oxaloyldihydrazones, 1,10-phenanthroline and 2,2′-bipyridine
Syiemlieh, Ibanphylla
Kumar, Arvind
Kurbah, Sunshine D.
Lal, Ram A.
JOURNAL OF MOLECULAR STRUCTURE, 2018, 1166 : 252 - 261
[5] Electronic and Photophysical Properties of Platinum(II) Biphenyl Complexes Containing 2,2′-Bipyridine and 1,10-Phenanthroline Ligands
Rillema, D. Paul
Cruz, Arvin J.
Moore, Curtis
Siam, Khamis
Jehan, A.
Base, Derek
Nguyen, T.
Huang, Wei
INORGANIC CHEMISTRY, 2013, 52 (02) : 596 - 607
[6] Synthesis, crystal structure and cytotoxic activity of 2,2′-bipyridine / 1,10-Phenanthroline based Copper(II) complexes with diphenylphosphinic acid
Savinykh, Polina E.
Golubeva, Yuliya A.
Smirnova, Ksenia S.
Klyushova, Lyubov' S.
Berezin, Alexey S.
Lider, Elizaveta, V
POLYHEDRON, 2024, 261
[7] Synthesis and Characterization of Dioxomolybdenum(VI) Complexes with 1,10-Phenanthroline and 2,2′-Bipyridyl
Khojasteh, R. R.
Saremi, Sajedeh Lotfalian
Ahmadzadeh, M.
ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (08) : 3769 - 3770
[8] Synthesis and Crystal Structures of Di-nuclear Zinc(II) Diphenate Complexes with 1,10-Phenanthroline and 2,2′-Bipyridine
Koo, Bon Kweon
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32 (08) : 2617 - 2622
[9] Synthesis, structure and spectroscopic properties of complexes of rare earth dithiocarbamates with 2,2'-bipyridyl or 1,10-phenanthroline
Su, CG
Tan, MY
Tang, N
Gan, XM
Wang, X
JOURNAL OF COORDINATION CHEMISTRY, 1996, 38 (03) : 207 - 218
[10] Synthesis and characterization of tris(2,2′-bipyridine) and tris(1,10-phenanthroline) copper(II) hexafluorophosphate.: crystal structure of the phenanthroline complex
Seco, JM
Garmendia, MJG
Quiros, M
JOURNAL OF COORDINATION CHEMISTRY, 2002, 55 (03) : 345 - 351

← 1 2 3 4 5 →