Binuclear cluster complexes of molybdenum containing 2,2′-bipyridine and 1,10-phenanthroline: Synthesis and structure

被引：0

作者：

A. L. Gushchin

Yu. L. Laricheva

N. I. Alferova

A. V. Virovets

M. N. Sokolov

机构：

[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division

[2] Novosibirsk State University,undefined

来源：

Journal of Structural Chemistry | 2013年 / 54卷

关键词：

binuclear clusters; molybdenum; polypyridine ligands; crystal structure; IR spectra;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

By the interaction between (Et4N)2[Mo2O2S8] and I2 in DMF with a subsequent addition of 2,2′-bipyridine or 1,10-phenanthroline, new binuclear complexes [Mo2O2S2I2(bipy)2] (1) and [Mo2O2S2I2(phen)2] (2) are obtained. The structure of [Mo2O2S2I2(bipy)2] is determined using single crystal X-ray diffraction. The compounds are characterized by elemental analysis and IR spectra. The [MoO(S2)2(bipy)] complex as a product of oxidative destruction of 1 is isolated and characterized.

引用

页码：752 / 758

页数：6

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