Chloromethylthio-Substituted Chromium(III), Cobalt(III), and Aluminum(III) Acetylacetonates

被引：0

作者：

I. V. Svistunova

N. P. Shapkin

G. M. Svistunov

机构：

[1] Far-Eastern State University,

来源：

Russian Journal of General Chemistry | 2001年 / 71卷

关键词：

Aluminum; Spectroscopy; Chloride; Mass Spectroscopy; Chromium;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

SCl-Substituted chromium(III), cobalt(III), and aluminum(III) acetylacetonates react with carbenes similarly to organylsulfenyl chlorides, with insertion of the carbenes into the S-Cl bond. Reaction with diazomethane gave chloromethylthio-substituted complexes whose structure was proved by IR, 1H NMR, and mass spectroscopy. The thermal oxidative degradation of the complexes was studied. Chlorination of SCH3-substituted acetylacetonates does not yield such complexes.

引用

页码：1355 / 1357

页数：2

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