Composite photocalysts based on the nanostructural titanium dioxide and zirconium phosphate

被引:0
作者
E. N. Krut’ko
T. N. Galkova
A. I. Kulak
机构
[1] National Academy of Sciences of Belarus,Institute of General and Inorganic Chemistry
来源
Russian Journal of Physical Chemistry A, Focus on Chemistry | 2008年 / 82卷
关键词
Photocatalytic Activity; High Photocatalytic Activity; Zirconium Phosphate; Composite Photocatalysts; Zirconyl Nitrate;
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学科分类号
摘要
A series of composite photocatalysts based on titanium dioxide deposited on the surface of a zirconium phosphate support were synthesized under different synthesis and heat-treatment conditions. The study of the photodestruction kinetics of Rhodamine C showed that the synthesized composites possess high photocatalytic activity that is competitive with the activity of a commercial Hombikat UV100 photocatalyst. The composites based on zirconium phosphate treated with isopropanol at the precipitation stage whereupon heated at 550°C exhibit the highest photocatalytic activity after heating at 750°C. It was found that such zirconium phosphate support has the largest specific surface area (270 m2/g). After heating at 550°C, the surface becomes more stable to the subsequent heating to 750°C, which is necessary for the most complete crystallization of TiO2 ensuring its high photocatalytic characteristics.
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页码:2219 / 2222
页数:3
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