Hydrogen-Bonded Structure of 2:1 TCNQ Salt of 2-Methyl-5-Phenyl-7,9-Dichloro-1,6-Diazaphenalene

被引：0
作者：
T. Murata
Y. Morita
K. Tamaki
K. Nakasuji
机构：
[1] Kyoto University,Division of Chemistry, Graduate School of Science
[2] Graduate School of Science,Department of Chemistry
[3] Osaka University,PRESTO
[4] Japan Science and Technology Agency (JST),undefined
来源：
Journal of Low Temperature Physics | 2006年 / 142卷
关键词：
Crystal Structure; Triad; Magnetic Material; Columnar Structure; TCNQ;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The crystal structure of 2:1 TCNQ salt of 2-methyl-5-phenyl-7,9-dichloro-1,6-diazaphenalene (1) was investigated for the construction of new hydrogen-bonded charge-transfer complexes. This salt was composed of neutral 1, protonated 1 (1·H+) and ionic TCNQ (TCNQ·−), and constructed a segregated structure with uniform π-stackings. The N–H···N≡C hydrogenbonding between 1/1·H+ and TCNQ·− formed the D-A-D triad, and connected the columnar structures.
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页码：425 / 428
页数：3
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