Novel electrospun luminescent nanofibers from cationic polyfluorene/cellulose acetate blend

被引:0
作者
Rebeca Vázquez-Guilló
Alex Calero
Artur J. M. Valente
Hugh D. Burrows
C. Reyes Mateo
Ricardo Mallavia
机构
[1] Universidad Miguel Hernandez de Elche,Instituto de Biología Molecular y Celular
[2] University of Coimbra,Department of Chemistry
来源
Cellulose | 2013年 / 20卷
关键词
Electrospinning; Cellulose acetate; Fluorene-based polymers; Polyelectrolyte; Nanofibers;
D O I
暂无
中图分类号
学科分类号
摘要
This work reports production of nanofibers of cellulose acetate (CA) via electrospinning (ES) technology. Optimal operating conditions to produce nanofibers have been found to involve CA solutions at 20 wt% concentration, flow rate 1.0 mL h−1, a distance between needle tip-collector target of 15 cm and an applied voltage at 20 kV. Under these experimental conditions, nanofibers were produced by ES a solution containing a low concentration of a luminescent fluorene-based cationic conjugated polyelectrolyte. Electronic and optical microscopies were used to characterize their morphology and the diameter of fibers (over 260 nm). Composite fibers with excellent luminescence properties have been obtained and studied in the solid state. Potential applications in a sensing device for nitrobenzene have been tested.
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页码:169 / 177
页数:8
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