Epoxidation and oxidation reactions using 1,4-butanediol dimethacrylate crosslinked polystyrene-supported tertiary butyl hydroperoxide

被引:0
作者
M. S. Sheela
K. Sreekumar
机构
[1] University of Kerala,Department of Chemistry
[2] Cochin University of Science and Technology,Department of Applied Chemistry
来源
Journal of Chemical Sciences | 2004年 / 116卷
关键词
Polystyrene-supported reagent; -butyl hydroperoxide; solid-phase organic reagent; recyclability; epoxidation; oxidation;
D O I
暂无
中图分类号
学科分类号
摘要
1,4-Butanediol dimethacrylate (1,4-BDDMA) crosslinked polystyrene-supported t-butyl hydroperoxide was employed in the epoxidation of olefins and oxidation of alcohols to carbonyl compounds. The reagent proved to be successful as a recyclable solid phase organic reagent with as much or more efficiency when compared to its monomeric counterpart. The extent of reaction was found to be dependent on various reaction parameters like solvent, temperature, molar concentration and presence of catalyst.
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页码:319 / 324
页数:5
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