Synthesis and structure of triple thorium phosphates with monazite structure

被引:0
作者
Alexander Knyazev
Ivan Savushkin
Ulmas Mirsaidov
Alexey Lukoyanov
Artem Oganov
机构
[1] Lobachevsky University,
[2] Nuclear and Radiation safety Agency,undefined
[3] Skolkovo Institute of Science and Technology,undefined
来源
Journal of Radioanalytical and Nuclear Chemistry | 2021年 / 327卷
关键词
Monazite; Thorium phosphate, M; LaTh(PO; ); Crystal structure; Rietveld method; IR spectroscopy;
D O I
暂无
中图分类号
学科分类号
摘要
Three monazites MIILaTh(PO4)3 (MII = Ca, Sr, Cd) have been studied both computationally and experimentally to determine the influence of the MII cation nature on monazite crystal structure and characteristics important for their use as matrix forms for immobilizing radioactive waste. Their crystal structures have been refined by the Rietveld method. Functional composition has been confirmed by IR spectroscopy. Thermal stability has been tested by DTA-TG.
引用
收藏
页码:1105 / 1112
页数:7
相关论文
共 50 条
  • [21] Synthesis, structure and luminescence properties of the europium-containing NASICON type phosphates
    Asabina, Elena
    Sedov, Vladislav
    Pet'kov, Vladimir
    Deyneko, Dina
    Kovalsky, Andrey
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2023, 105 (02) : 547 - 554
  • [22] Synthesis and characterisation of transition-metal-substituted gallium phosphates with the laumontite structure
    Bond, AD
    Chippindale, AM
    Cowley, AR
    Readman, JE
    ZEOLITES, 1997, 19 (5-6): : 326 - 333
  • [23] SEPARATION OF THORIUM FROM URANIUM IN MONAZITE BY PRECIPITATION METHOD
    Trinopiawan, Kurnia
    Sumiarti
    EKSPLORIUM-BULETIN PUSAT TEKNOLOGI BAHAN GALIAN NUKLIR, 2012, 33 (01): : 55 - 62
  • [24] Protonic conduction in rare earth orthophosphates with the monazite structure
    Kitamura, N
    Amezawa, K
    Tomii, Y
    Yamamoto, N
    SOLID STATE IONICS, 2003, 162 : 161 - 165
  • [25] Lanthanide Phosphates Prepared by Direct Precipitation and Hydrothermal Synthesis: Structure and Behavior during Heating
    Koryttseva, A. K.
    Orlova, A. I.
    Atopshev, A. A.
    Turchenko, V. A.
    Beskrovnyi, A. I.
    Murashov, A. A.
    Nokhrin, A. V.
    INORGANIC MATERIALS, 2023, 59 (08) : 842 - 850
  • [26] Lanthanide Phosphates Prepared by Direct Precipitation and Hydrothermal Synthesis: Structure and Behavior during Heating
    A. K. Koryttseva
    A. I. Orlova
    A. A. Atopshev
    V. A. Turchenko
    A. I. Beskrovnyi
    A. A. Murashov
    A. V. Nokhrin
    Inorganic Materials, 2023, 59 : 842 - 850
  • [27] Conversion of thorium(IV) oxide into thorium(IV) trifluoromethanesulfonate: Crystal structure of thorium(IV) trifluoromethanesulfonate dihydrate
    Lyczko, Krzysztof
    Lyczko, Monika
    Walo, Marta
    Lipkowski, Janusz
    INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 24 : 234 - 236
  • [28] Investigation of the alkaline earth phosphates: Synthesis and crystal structure of a new strontium hydrogen phosphate form
    Ben Taher, L
    Smiri, L
    Laligant, Y
    Maisonneuve, V
    JOURNAL OF SOLID STATE CHEMISTRY, 2000, 152 (02) : 428 - 434
  • [29] Monazite structure from dehydrated CaSeO4•2H2O
    Crichton, W. A.
    Mueller, H.
    Merlini, M.
    Roth, T.
    Detlefs, C.
    MINERALOGICAL MAGAZINE, 2010, 74 (01) : 127 - 139
  • [30] Synthesis and structure of phosphates M0.5Ti2(PO4)3
    E. A. Asabina
    I. O. Glukhova
    V. I. Pet’kov
    E. Yu. Borovikova
    A. M. Koval’skii
    Russian Journal of General Chemistry, 2017, 87 : 684 - 689