Synthesis and structure of triple thorium phosphates with monazite structure

被引:0
|
作者
Alexander Knyazev
Ivan Savushkin
Ulmas Mirsaidov
Alexey Lukoyanov
Artem Oganov
机构
[1] Lobachevsky University,
[2] Nuclear and Radiation safety Agency,undefined
[3] Skolkovo Institute of Science and Technology,undefined
来源
Journal of Radioanalytical and Nuclear Chemistry | 2021年 / 327卷
关键词
Monazite; Thorium phosphate, M; LaTh(PO; ); Crystal structure; Rietveld method; IR spectroscopy;
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学科分类号
摘要
Three monazites MIILaTh(PO4)3 (MII = Ca, Sr, Cd) have been studied both computationally and experimentally to determine the influence of the MII cation nature on monazite crystal structure and characteristics important for their use as matrix forms for immobilizing radioactive waste. Their crystal structures have been refined by the Rietveld method. Functional composition has been confirmed by IR spectroscopy. Thermal stability has been tested by DTA-TG.
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页码:1105 / 1112
页数:7
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