Synthesis, molecular and electronic structures of half-sandwich ruthenium(II) complexes with pyrimidine-based ligands

被引：0

作者：

J. G. Małecki

机构：

[1] Institute of Chemistry,Department of Crystallography

[2] University of Silesia,undefined

来源：

Transition Metal Chemistry | 2010年 / 35卷

关键词：

Ruthenium; RuCl2; Mulliken Population Analysis; Energy Decomposition Analysis; Ruthenium Atom;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The complexes [(C6H6)RuCl2(Hmtp)] and [(C6H6)RuCl2(C4H4N2)] have been prepared and studied by IR, 1H NMR, UV–VIS spectroscopy and X-ray crystallography. The complexes were prepared by reactions of [(C6H6)RuCl2]2 with 7-hydroxy-5-methyl[1,2,4]triazolo[1,5-a]pyrimidine (Hmtp) and pyrimidine, respectively, in methanol. The electronic structures and UV–Vis spectra of the complexes have been calculated using the TD–DFT method.

引用

页码：801 / 808

页数：7

共 50 条

[1] Synthesis, molecular and electronic structures of half-sandwich ruthenium(II) complexes with pyrimidine-based ligands
Malecki, J. G.
TRANSITION METAL CHEMISTRY, 2010, 35 (07) : 801 - 808
[2] Synthesis, structures and catalytic activities of half-sandwich ruthenium complexes based on Schiff Base ligands
Jia, Wei-Guo
Zhang, Hui
Zhang, Tai
Ling, Shuo
INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 66 : 15 - 18
[3] Synthesis, Structural and Biological Studies of Some Half-Sandwich d6-Metal Complexes with Pyrimidine-Based Ligands
Aradhyula, Basava Punna Rao
Kalidasan, Mahesh
Gangele, Krishnakant
Deb, Debojit K.
Shepherd, Samanta L.
Phillips, Roger M.
Poluri, Krishna Mohan
Kollipara, Mohan Rao
CHEMISTRYSELECT, 2017, 2 (06): : 2065 - 2076
[4] Half-sandwich ruthenium complexes of pentafluorobenzenethiolato ligands
Shawakfeh, Khaled
El-khateeb, Mohammad
Taher, Deeb
Goerls, Helmar
Weigand, Wolfgang
TRANSITION METAL CHEMISTRY, 2008, 33 (03) : 387 - 391
[5] Half-sandwich ruthenium complexes of pentafluorobenzenethiolato ligands
Khaled Shawakfeh
Mohammad El-khateeb
Deeb Taher
Helmar Görls
Wolfgang Weigand
Transition Metal Chemistry, 2008, 33 : 387 - 391
[6] Half-sandwich ruthenium(II) complexes with N- and N,(N,O)-donor ligands: molecular, electronic structures, and computational study
Malecki, J. G.
STRUCTURAL CHEMISTRY, 2012, 23 (02) : 461 - 472
[7] Half-sandwich ruthenium(II) complexes with N- and N,(N,O)-donor ligands: molecular, electronic structures, and computational study
J. G. Małecki
Structural Chemistry, 2012, 23 : 461 - 472
[8] Ruthenium(II) pentamethylcyclopentadienyl half-sandwich carbene complexes with polypyridyl ligands
Albertin, Gabriele
Antoniutti, Stefano
Bortoluzzi, Marco
Castro, Jesus
Trevisan, Mauro
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 848 : 1 - 9
[9] Synthesis of new half-sandwich ruthenium(II) complexes bearing alkenyl- and alkynylphosphane ligands
Díez, J
Gamasa, MP
Gimeno, J
Lastra, E
Villar, A
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (01) : 78 - 87
[10] Cationic half-sandwich ruthenium(II) complexes with cyclopentadienyl-phosphine ligands
Doppiu, A
Englert, U
Salzer, A
INORGANICA CHIMICA ACTA, 2003, 350 : 435 - 441

← 1 2 3 4 5 →