Synthesis, molecular and electronic structures of half-sandwich ruthenium(II) complexes with pyrimidine-based ligands

被引：0

作者：

J. G. Małecki

机构：

[1] Institute of Chemistry,Department of Crystallography

[2] University of Silesia,undefined

来源：

Transition Metal Chemistry | 2010年 / 35卷

关键词：

Ruthenium; RuCl2; Mulliken Population Analysis; Energy Decomposition Analysis; Ruthenium Atom;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The complexes [(C6H6)RuCl2(Hmtp)] and [(C6H6)RuCl2(C4H4N2)] have been prepared and studied by IR, 1H NMR, UV–VIS spectroscopy and X-ray crystallography. The complexes were prepared by reactions of [(C6H6)RuCl2]2 with 7-hydroxy-5-methyl[1,2,4]triazolo[1,5-a]pyrimidine (Hmtp) and pyrimidine, respectively, in methanol. The electronic structures and UV–Vis spectra of the complexes have been calculated using the TD–DFT method.

引用

页码：801 / 808

页数：7

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