Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition

被引：0
作者：
Cong Ye
Yanbin Zhang
Aishun Ding
Yong Hu
Hao Guo
机构：
[1] Fudan University,Department of Chemistry
[2] Shanghai Children’s Hospital,Department of Neonatology
[3] Shanghai Jiao Tong University,undefined
来源：
Scientific Reports | / 8卷
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摘要：
We report herein a visible light sensitizer-catalyzed aerobic oxidation of thioethers, affording sulfoxides in good to excellent yields. The loading of the catalyst was as low as 0.1 mol%. The selectivity was excellent. Mechanism studies showed both singlet oxygen and superoxide radical anion were likely involved in this transformation.
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