Stability of the valinomycin-rubidium complex in water saturated nitrobenzene

被引：0

作者：

M. Daňková

E. Makrlík

P. Vaňura

机构：

[1] Charles University,Faculty of Education

[2] Prague Institute of Chemical Technology,undefined

来源：

Journal of Radioanalytical and Nuclear Chemistry | 1997年 / 221卷

关键词：

Physical Chemistry; Inorganic Chemistry; Aqueous Phase; Stability Constant; Nitrobenzene;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

From the extraction experiments and γ-activity measurements, the extraction constant corresponding to the Rb+(aq)+CsL+(nb)⇆RbL+(nb)+Cs+(aq) equilibrium in the two-phase water-nitrobenzene system (L=valinomycin; aq=aqueous phase, nb=nitrobenzene phase) was evaluated in the form logKex (Rb+, CsL+)=0.9. Further, the stability constant of the valinomycin-rubidium complex in nitrobenzene saturated with water was calculated as log βnb(RbL+)=11.7.

引用

页码：251 / 253

页数：2

共 28 条

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