1,1-Dihalo-2-benzycyclopropanes in reaction with nitrous acid

被引：0
作者：
A. Z. Kadzhaeva
E. V. Trofimova
R. A. Gazzaeva
A. N. Fedotov
S. S. Mochalov
机构：
[1] Chair of Organic Chemistry,
来源：
Moscow University Chemistry Bulletin | 2009年 / 64卷 / 1期
关键词：
Cyclopropane; Nitro Compound; Dibromide; Isoxazoles; Cyclopropane Ring;
D O I：
10.3103/S0027131409010064
中图分类号：
学科分类号：
摘要：
Interaction of 1,1-dichoro and 1,1-dibromo-2-benzylcyclopropanes with nitrous acid generated in situ was studied. It was shown that both nitration of the aromatic ring and heterocyclization of 1,1-dihalo-2-benzylcyclopropanes take place. Heterocyclization is initiated by opening of the cyclopropane ring in the reaction with nitrosyl cation. The nature of halogen atom in the cyclopropane ring affects the regioselectivity of the reactions.
引用
收藏
页码：28 / 31
页数：3
相关论文
共 39 条
[1]  
Al’khamdan M.(1994)undefined Vestn. Mosk. Un-Ta, Ser. 2. Khimiya 35 357-undefined
[2]  
Saginova L.G.(1997)undefined J. Org. Chem 62 5229-undefined
[3]  
Petrosyan V.S.(1957)undefined Vestn. Mosk. Un-ta, Ser. 2., Khimiya 5 145-undefined
[4]  
Lin S.-T.(1957)undefined Materialy X Vsesoyuznogo soveshchaniya po spektroskopii 1 64-undefined
[5]  
Kuo S.-H.(1998)undefined ZhOrKh 34 1379-undefined
[6]  
Yang F.-M.(1988)undefined ZhOrKh 24 1413-undefined
[7]  
Levina R.Ya.(1981)undefined J. Org. Chem. 46 3056-undefined
[8]  
Shabarov Yu.S.(2004)undefined ZhOrKh 40 1146-undefined
[9]  
Shanazarov K.S.(2003)undefined Chem. Rev 103 1151-undefined
[10]  
Aleksanyan V. T.(2005)undefined Vestn. Mosk. Un-ta, Ser. 2, Khimiya 46 349-undefined
1234