The synthesis and structural characterisation of [IrCl(COD)(PEt3)n], n = 1 or 2, and orthometallated Vaska's compound, [IrHCl(CO)(PPh3)η2-PPh2(C6H4)]

被引：0

作者：

Markus Brym

Cameron Jones

机构：

[1] University of Wales – Cardiff,Department of Chemistry

来源：

Transition Metal Chemistry | 2003年 / 28卷

关键词：

Physical Chemistry; Crystal Structure; Inorganic Chemistry; Catalysis; Carbonyl;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Two iridium(I) complexes, [IrCl(COD)(PEt3)n], n = 1 or 2, have been prepared and structurally characterised. Although [IrCl(COD)(PEt3)] is a known compound the spectroscopic data on both compounds is presented and discussed. In addition, the X-ray crystal structure of the previously described orthometallated isomer of Vaska's compound, [IrHCl(CO)(PPh3)η2-PPh2(C6H4)], is reported to show the hydride ligand trans- to the carbonyl ligand.

引用

页码：595 / 599

页数：4

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