The synthesis and structural characterisation of [IrCl(COD)(PEt3)n], n = 1 or 2, and orthometallated Vaska's compound, [IrHCl(CO)(PPh3)η2-PPh2(C6H4)]

被引：0
|
作者：
Markus Brym
Cameron Jones
机构：
[1] University of Wales – Cardiff,Department of Chemistry
来源：
Transition Metal Chemistry | 2003年 / 28卷
关键词：
Physical Chemistry; Crystal Structure; Inorganic Chemistry; Catalysis; Carbonyl;
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学科分类号：
摘要：
Two iridium(I) complexes, [IrCl(COD)(PEt3)n], n = 1 or 2, have been prepared and structurally characterised. Although [IrCl(COD)(PEt3)] is a known compound the spectroscopic data on both compounds is presented and discussed. In addition, the X-ray crystal structure of the previously described orthometallated isomer of Vaska's compound, [IrHCl(CO)(PPh3)η2-PPh2(C6H4)], is reported to show the hydride ligand trans- to the carbonyl ligand.
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页码：595 / 599
页数：4
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