Thermal explosion of a reactive mixture under conditions of oscillating ambient temperature

被引:0
|
作者
V. A. Gorel’skii
A. A. Yashchuk
A. S. Shteinberg
机构
[1] Institute of Applied Mathematics and Mechanics of the Tomsk State University,Semenov Institute of Chemical Physics
[2] Russian Academy of Sciences,undefined
来源
Russian Journal of Physical Chemistry B | 2010年 / 4卷
关键词
thermal explosion; harmonic oscillations of temperature;
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学科分类号
摘要
The problem of the thermal explosion of a finite volume of a reactive material in a medium with harmonically oscillating temperature is solved in the classical formulation. A kind of resonance is shown to arise when the oscillation period is commensurate with the adiabatic induction period of thermal explosion at the mean ambient temperature. At both high and very low oscillation frequencies, the critical condition parameter and induction period are only slightly affected by ambient temperature oscillations. By contrast, at moderately low frequencies, even small-amplitude oscillations of ambient temperature can strongly influence the critical condition and, especially, induction period of thermal explosion.
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页码:755 / 759
页数:4
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