Distribution equilibria of Pb and Cu between CaO-SiO2-Al2O3 melts and liquid copper

被引:0
作者
Kenji Matsuzaki
Takaaki Ishikawa
Takayuki Tsukada
Kimihisa Ito
机构
[1] Mitsui Mining & Smelting,the Department of Materials Science and Engineering
[2] Waseda University,undefined
来源
Metallurgical and Materials Transactions B | 2000年 / 31卷
关键词
Material Transaction; Activity Coefficient; Oxygen Partial Pressure; Distribution Ratio; Lead Oxide;
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摘要
The distribution equilibria of lead and copper between CaO-SiO2-Al2O3 melts and liquid copper were measured at 1623 K under a controlled H2-CO2 atmosphere. The distribution ratios were plotted against the oxygen partial pressure, and reasonable oxide forms dissolved in the melts were estimated from the slopes of the plots. The activity coefficients of lead oxide (PbO) and cuprous oxide (CuO0.5) increased with increasing slag basicity, defined by XCaO/XSiO2. The temperature dependence of the activity coefficients of lead oxide and cuprous oxide was also measured.
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页码:1261 / 1266
页数:5
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