Scaled particle theory for bulk and confined fluids: A review

被引:0
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作者
Wei Dong
XiaoSong Chen
机构
[1] Laboratoire de Chimie,Université de Lyon, CNRS, Ecole Normale Supérieure de Lyon, Université Lyon 1
[2] Chinese Academy of Sciences,State Key Laboratory of Theoretical Physics, Institute of Theoretical Physics
关键词
fluids confined in porous media; scaled particle theory; hard sphere fluids;
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摘要
More than half a century after its first formulation by Reiss, Frisch and Lebowitz in 1959, scaled particle theory (SPT) has proven its immense usefulness and has become one of the most successful theories in liquid physics. In recent years, we have strived to extend SPT to fluids confined in a variety of random porous matrices. In this article, we present a timely review of these developments. We have endeavored to present a formulation that is pedagogically more accessible than those presented in various original papers, and we hope this benefits newcomers in their research work. We also use more consistent notations for different cases. In addition, we discuss issues that have been scarcely considered in the literature, e.g., the one-fluid structure of SPT due to the isomorphism between the equation of state for a multicomponent fluid and that for a one-component fluid or the pure-confinement scaling relation that provides a connection between a confined and a bulk fluid.
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