Effect of the type of crystal lattice in nickel(II) and copper(II) macrocyclic carboxylates on absorption of copper amine complexes from solutions

被引：0
作者：
I. L. Andriichuk
L. V. Tsymbal
Ya. D. Lampeka
机构：
[1] National Academy of Sciences of Ukraine,L. V. Pisarzhevskii Institute of Physical Chemistry
来源：
Theoretical and Experimental Chemistry | 2010年 / 46卷
关键词：
azamacrocyclic complexes; nickel; carboxylates; nanoparticles; copper(II) ammine complex; copper(II) sulfide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
We have established that crystalline nickel-containing metal–organic frameworks (MOFs) bind the complex [Cu(NH3)4](ClO4)2 from acetonitrile solutions and do not react with [Cu(en)2](ClO4)2. The MOF/copper ammine complex ratio in the products after reaching saturation is determined by the crystal lattice structures of the compounds, and increases from 1.2 (one-dimensional coordination polymer, 1D CP) to 3.2 (2D CP)and 3.9 (ionic MOF) moles of copper ammine complex per formula unit of sorbent. We have shown that it is possible to convert the bound ammine complex to nanosized copper(II) sulfide by treatment with sodium sulfide.
引用
收藏
页码：58 / 63
页数：5
相关论文
共 34 条
  • [1] Lampeka Ya D(2004)undefined Teor. Éksp. Khim. 40 331-356
  • [2] Tsymbal LV(2007)undefined Adv. Inorg. Chem. 59 39-79
  • [3] Suh MP(2009)undefined Teor. Éksp. Khim. 45 67-87
  • [4] Moon HR(2009)undefined Teor. Éksp. Khim. 45 265-288
  • [5] Kolotilov SV(2009)undefined J. Mater. Chem. 19 1314-1319
  • [6] Pavlishchuk VV(2009)undefined J. Mater. Chem. 19 7626-7631
  • [7] Kolotilov SV(2001)undefined Chem. Eur. J. 7 303-313
  • [8] Pavlishchuk VV(2001)undefined J. Inclus. Phenom. Macrocyclic Chem. 41 155-162
  • [9] Esken D(2007)undefined Teor. Éksp. Khim. 43 124-129
  • [10] Zhang X(2009)undefined J. Am. Chem. Soc. 131 18196-18197
1234