Selective liquid sorption properties of hydrophobized graphite oxide nanostructures

被引:139
|
作者
Dékány I. [1 ]
Krüger-Grasser R. [2 ]
Weiss A. [2 ]
机构
[1] Department of Colloid Chemistry, Attila József University
[2] Institute of Inorganic Chemistry, University of Munich
关键词
Graphite oxides; Liquid adsorption; Microcalorimetry; Nanostructures; Swelling;
D O I
10.1007/s003960050283
中图分类号
学科分类号
摘要
Hydrophilic graphite oxide (GO) of lamellar structure was prepared by oxidation of graphite; the thickness of the individual lamellae was 6.1 Å. GO was hydrophobized by n-alkylammonium cations, and the GO-organocomplex nanocomposites were swollen in organic solvents of various polarities (ethanol, toluene, cyclohexane, n-heptane) and their binary mixtures. The binary liquid composition determined the size (15-45 Å) of the lamellar GO nanostructures. Interlamellar swelling was quantitatively characterized by XRD experiments, determination of liquid sorption excess isotherms and flow microcalorimetry.
引用
收藏
页码:570 / 576
页数:6
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