Novel Synthesis of Linear Polyimides by Palladium-Catalyzed Carbonylation Polycondensation of Aromatic Diamides, Aromatic Dibromides, and Carbon Monoxide

被引：0
作者：
Masaru Yoneyama
Toshihisa Nasa
Kozo Arai
机构：
[1] Gunma University,Department of Biological and Chemical Engineering, Faculty of Engineering
来源：
Polymer Journal | 1998年 / 30卷
关键词：
Palladium Catalysts; Carbonylation Polycondensation; Linear Polyimides; Carbon Monoxide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new and convenient method was found for the synthesis of linear imides by the palladium-catalyzed carbonylation condensation of aromatic amides with aromatic bromides and carbon monoxide. By the extension of this reaction to polymerization, a novel approach to the preparation of linear polyimides was developed. The effects of polymerization conditions, such as kinds and amounts of base and palladium catalyst, and polymerization temperature are discussed in detail. Large excess PPh3 was required to obtain a homogeneous solution. The reactivity of aromatic diamides was found to be low for this carbonylation polycondensation.
引用
收藏
页码：697 / 701
页数：4
相关论文
共 28 条
  • [21] Indole synthesis: palladium-catalyzed C-H bond amination via reduction of nitroalkenes with carbon monoxide
    Hsieh, Tom H. H.
    Dong, Vy M.
    TETRAHEDRON, 2009, 65 (16) : 3062 - 3068
  • [22] Palladium-catalyzed carbonylation of aryl bromides using microwave heating and bis[CP-Fe(II)-(CO)2] as a carbon monoxide source
    Roy, Tamal
    Rydfjord, Jonas
    Savmarker, Jonas
    Nordeman, Patrik
    TETRAHEDRON LETTERS, 2018, 59 (13) : 1230 - 1232
  • [23] Binuclear palladium(I) and platinum(I) dimers stabilized by aromatic ligands: synthesis, structural characterization and reactivity with carbon monoxide
    Gorlov, M
    Fischer, A
    Lars, K
    INORGANICA CHIMICA ACTA, 2003, 350 : 449 - 454
  • [24] Palladium-Catalyzed Three-Component Coupling Reaction of Benzyl Chlorides, Allyltributylstannane, and Carbon Monoxide: Efficient Synthesis of α,β-Unsaturated Ketones
    Zhang Xin
    Feng Xiujuan
    Liu Hesong
    Qin Yuhu
    Dai Yao
    CHINESE JOURNAL OF CATALYSIS, 2012, 33 (03) : 523 - 529
  • [25] PALLADIUM-CATALYZED N,N'-DIPHENYLUREA SYNTHESIS FROM NITROBENZENE, ANILINE, AND CARBON-MONOXIDE .4. LIGAND EFFECTS
    LEE, CW
    LEE, JS
    LEE, SM
    KIM, KD
    CHO, NS
    OH, JS
    JOURNAL OF MOLECULAR CATALYSIS, 1993, 81 (01): : 17 - 25
  • [26] Computational Study of the Palladium-Catalyzed Carbonylative Synthesis of Aromatic Acid Chlorides: The Synergistic Effect of PtBu3 and CO on Reductive Elimination
    Quesnel, Jeffrey S.
    Moncho, Salvador
    Ylijoki, Kai E. O.
    Torres, Gerardo Martin
    Brothers, Edward N.
    Bengali, Ashfaq A.
    Arndtsen, Bruce A.
    CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (42) : 15107 - 15118
  • [27] A new synthetic method of 1,4-dihydro-2H-3,1-benzoxazin-2-ones:: Selenium-catalyzed reductive carbonylation of aromatic nitro compounds with carbon monoxide
    Nishiyama, Y
    Naitoh, Y
    Sonoda, N
    SYNLETT, 2004, (05) : 886 - 888
  • [28] A NEW PALLADIUM-CATALYZED SYNTHESIS OF 3,4-DISUBSTITUTED COUMARINS FROM 3-ALKENOATES OF ORTHO-IODOPHENOL, PHENYLACETYLENE AND CARBON-MONOXIDE
    CATELLANI, M
    CHIUSOLI, GP
    FAGNOLA, MC
    SOLARI, G
    TETRAHEDRON LETTERS, 1994, 35 (32) : 5923 - 5926
123