Crystal structure of dinuclear azide-bridged copper(II) complex [Cu2((3,4-MeO-Ba)2En)2(μ1,1-N3)2(N3)2]{(3,4-MeO-Ba)2En=N,N′-Bis(3,4-dimethoxybenzylidene)-1,2-ethanediamine}

被引：0
作者：
S. Jalali Akerdi
G. Grivani
H. Stoeckli-Evans
A. D. Khalaji
机构：
[1] Damghan University,School of Chemistry
[2] University of Neuch@atel,Institute of Physics, Laboratory Physical Chemistry
[3] Golestan University,Department of Chemistry, Faculty of Science
来源：
Russian Journal of Coordination Chemistry | 2011年 / 37卷
关键词：
Schiff Base Ligand; Azido; Dinuclear Copper; Ethanediamine; Diaminoethane;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New dinuclear copper(II)-azido complex [Cu2((3,4-MeO-Ba)2En)2(μ1,1-N3)2(N3)2] (I) ((3,4-MeO-Ba)2En = N,N′-bis(3,4-dimethoxybenzylidene)-1,2-diaminoethane) has been synthesized and characterized by elemental analyses, FT-IR spectroscopy, and X-ray single-crystal diffraction. Complex I consists of a dinuclear unit that represents a new example of a copper(II)-azido compound and the Cu2+ ions are bridged by two azido ions in a double end-on fashion, consisting of two terminally bonded azido ligands. The Schiff base ligand (3,4-MeO-Ba)2En is chelated by two imino nitrogen atoms.
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页码：394 / 398
页数：4
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