Electrocatalytic transformation of dialkyl malonates and arylidene- or alkylidenemalononitriles into dialkyl esters of 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylic acids

被引:0
作者
M. N. Elinson
S. K. Feducovich
T. A. Zaimovskaya
A. N. Vereshchagin
S. V. Gorbunov
G. I. Nikishin
机构
[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry
[2] Russian Academy of Sciences,A. V. Topchiev Institute of Petrochemical Synthesis
来源
Russian Chemical Bulletin | 2005年 / 54卷
关键词
electrolysis; electrocatalytic transformation; dialkyl malonates; arylidenemalononitriles; alkylidenemalononitriles; mediators; substituted cyclopropanes;
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学科分类号
摘要
Electrolysis of alcoholic solutions of dialkyl malonates and arylidene- or alkylidenemalononitriles in the presence of NaBr in an undivided cell gave dialkyl esters of 3-substituted 2,2-dicyanocyclopropane-1,1-dicarboxylic acids in 60–90% yields.
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页码:1593 / 1598
页数:5
相关论文
共 44 条
[1]  
Donaldson W. A.(2001)undefined Tetrahedron 57 8589-undefined
[2]  
Crosby J.(1991)undefined Tetrahedron 47 4789-undefined
[3]  
Elinson M. N.(1993)undefined Tetrahedron Lett. 33 5795-undefined
[4]  
Lizunova T. L.(1991)undefined Tetrahedron Lett. 32 2655-undefined
[5]  
Ugrak B. I.(1945)undefined Arkiv. Kemi 20B 8-undefined
[6]  
Dekaprilevich M. O.(2000)undefined Tetrahedron 56 3063-undefined
[7]  
Nikishin G. I.(1998)undefined Izv. Akad. Nauk, Ser. Khim. 47 1165-undefined
[8]  
Nikishin G. I.(2000)undefined Tetrahedron Lett. 41 4937-undefined
[9]  
Elinson M. N.(2003)undefined Izv. Akad. Nauk, Ser. Khim. 52 2117-undefined
[10]  
Lizunova T. L.(1990)undefined Izv. Akad. Nauk, Ser. Khim. 39 2783-undefined