Synthesis and Structure of Copper(II) Phosphonodithioite Complexes

被引:0
|
作者
L. I. Kursheva
O. N. Kataeva
S. V. Perova
E. S. Batyeva
O. G. Sinyashin
R. Freilich
机构
[1] Russian Academy of Sciences,Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
[2] University of Munster,Institute of Organic Chemistry
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关键词
Copper; Spectroscopy; Diethyl; CuBr; Monodentate Coordination;
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学科分类号
摘要
A series of new complexes of CuBr with phosphonodithioites were prepared and characterized by NMR and IR spectroscopy. As shown by single crystal X-ray diffraction, diethyl tert-butylphosphonodithioite forms with CuBr a tetrameric cubane-like complex with the monodentate coordination of the organophosphorus ligand via the P atom.
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页码:851 / 855
页数:4
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