Catalytic efficiency of the eggshell calcined and enriched with glycerin in the synthesis of biodiesel from frying residual oil

Currently, there are several studies using calcium oxide, calcium alkoxide, and calcium hydroxide for biodiesel production. However, there is still a lack of studies highlighting the use of calcium diglyceroxide (calcium oxide enriched with glycerin in the presence of methanol) as a catalyst in the transesterification process. Therefore, the present work aimed to investigate the catalytic efficiency and reutilization of the eggshell calcined and enriched with glycerin and methanol (ECEG), in the synthesis of methylic esters from frying residual oil. As a result, thermochemically modified eggshells showed catalytic efficiency during methylic transesterification of residual oils in mass concentrations of 15%, 5%, 3%, and 1% due to the presence of a high level of esters (97.39, 96.97, 97.75, and 92.96%, respectively). The initial concentration of the enriched eggshell used in methanolysis had a direct effect on the final ester mixture. A 15% increase in the water content of the frying oil contributed to an increase in the ester content. The ECEG was reactive and efficient for four reaction cycles (without reactivation of the catalytic sites) due to the evidence of a high ester content (97.85%, 98.67%, 98.89%, 98.46%), reaching the standard quality of worldwide biodiesel regulations.