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An appreciation of free radical chemistry part 5: Free radicals in organic synthesis
被引：0
作者：
G Nagendrappa
机构：
[1] Bangalore University,Department of Chemistry Central College Campus
来源：
关键词：
Atom transfer;
radical cyclisation;
radical substitution;
radical cascade;
natural products;
carbohydrates;
morphine hirsutene;
triethyl borane;
stereospecific reactions;
D O I：
10.1007/BF02866748
中图分类号：
学科分类号：
摘要：
Free radical synthetic methodology has grown by leaps and bounds in just about two decades. The limit to which the scope of free radical synthesis can go is restricted only by the imagination of the synthetic chemist. It greatly simplifies a synthetic sequence, makes use of readily available, relatively inexpensive reactants and reagen-ts; the transformations are selective, involve fewer steps, the yields are good, the reaction conditions are mild, etc. Therefore, such free radical reactions truly qualify to be called “Green Chemistry”.
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页码：80 / 90
页数：10
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