Langmuir–Blodgett films and optical second-harmonic generation of a crowned [60]fulleropyrrolidine

被引:0
作者
Z. Guo
Y. Li
Z. Ge
J. Yan
D. Zhu
J. Si
P. Ye
机构
[1] Center for Molecule Science,
[2] Institute of Chemistry,undefined
[3] Chinese Academy of Sciences,undefined
[4] Beijing 100080,undefined
[5] P.R. China,undefined
[6] Institute of Physics,undefined
[7] Chinese Academy of Sciences,undefined
[8] Beijing 100080,undefined
[9] P.R. China,undefined
来源
Applied Physics B | 2000年 / 71卷
关键词
PACS: 74.70.Wz; 42.70.Nq;
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摘要
The Langmuir and Langmuir–Blodgett (LB) films of a novel crowned [60]fullero-pyrrolidine (CFP) were produced in different conditions. Macroscopic second-harmonic generation of the LB film was investigated by means of AM1 Hamiltonian as well as experiments. The monolayer LB film displayed a periodic fringe pattern. A linear dependence of second-harmonic intensity on the number of layers was observed. The second-order molecular susceptibility χ(2) and hyperpolarizability β were evaluated to be 3.2×10−8 and 8.3×10−29 esu.
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页码:545 / 548
页数:3
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