Synthesis and photochromic properties of 4-[2-(anthracen-9-yl)-5-methyloxazolyl] fulgide

被引：0
|
作者：
V. P. Rybalkin
E. N. Shepelenko
V. V. Tkachev
G. V. Shilov
S. K. Balenko
A. V. Tsukanov
L. L. Popova
A. D. Dubonosov
S. M. Aldoshin
V. A. Bren’
V. I. Minkin
机构：
[1] Rostov State University,Institute of Physical and Organic Chemistry
[2] Russian Academy of Sciences,Institute of Problems of Chemical Physics
[3] Russian Academy of Sciences,Southern Scientific Center
来源：
Russian Chemical Bulletin | 2006年 / 55卷
关键词：
fulgide; synthesis; structure; photochromism;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New photochromic fulgide, viz., 4-{1-[2-(anthracen-9-yl)-5-methyloxazol-4-yl]ethylidene}-3-isopropylidenetetrahydrofuran-2,5-dione, with fluorescent properties was synthesized. Studies by electronic, IR, and 1H NMR spectroscopy and X-ray diffraction demonstrated that this fulgide exists in the Z form. Light irradiation of its solutions at a wavelength of 365 nm causes Z/E isomerization giving rise to the thermally stable cyclic form. The latter is transformed into the starting E isomer under light irradiation at λ = 436 nm.
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页码：101 / 105
页数：4
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