Synthesis and crystal structure of a new Schiff base ligand and its cobalt(II) complex

被引：0

作者：

Y. G. Li

X. W. Dong

R. Ai

X. L. Xu

H. L. Zhu

机构：

[1] Wuhan Textile University,School of Chemistry and Chemical Engineering, Engineering Research Center for Clean Production of Textile Printing, Ministry of Education

来源：

Russian Journal of Coordination Chemistry | 2011年 / 37卷

关键词：

Schiff Base; Schiff Base Ligand; Schiff Base Complex; Crystallographic Parameter; Single Molecule Magnet;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The crystal structures of cobalt(II) Schiff base complex (CoIIL2 · H2O) and Schiff base ligand 3,5-dichlorosalicylidene-2-chlorophenylmethylamine (HL) have been determined by single-crystal X-ray analysis. The geometry around cobalt in CoIIL2 · H2O is distorted tetrahedral. CoIIL2 · H2O crystallizes in the monoclinic system, in space group C2/c, with crystallographic parameters: a = 12.9143(16) Å, b = 8.8326(16) Å, c = 25.115(3) Å, β = 92.791(10)°, V = 2861.4(7) Å3, Z = 4, F(000) = 1420, and the final R indices (I > 2σ(I)) are R1 = 0.0440, wR2 = 0.1272. HL crystallizes in the monoclinic system, in space group P21/c, with crystallographic parameters: a = 11.9764(15), b = 8.2331(10), c = 14.2211(17) Å, β = 98.723(6)°, V = 1386.0(3) Å3, Z = 4, F(000) = 640, and the final R indices (I > 2σ(I)) are R1 = 0.0397, wR2 = 0.1018.

引用

页码：523 / 527

页数：4

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