Nature of paramagnetic centers in anodic aluminum oxide formed in a solution of tartaric acid

被引:0
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作者
K. V. Chernyakova
M. I. Ivanovskaya
I. I. Azarko
I. A. Vrublevskii
机构
[1] Belarussian State University of Informatics and Radioelectronics,Scientific Research Institute of Physical and Chemical Problems
[2] Belarussian State University,undefined
[3] Belarussian State University,undefined
关键词
anodic aluminum oxide; tartaric acid; EPR spectroscopy;
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摘要
Films of anodic aluminum oxide, prepared in an aqueous solution of 0.4 M tartaric acid, are studied by means of electron paramagnetic resonance (EPR) before and after heating at 200–700°C. The presence of a carbon radical is established in the films (g factor, 2.0027 ± 0.0002). The nature and conditions of its formation during the electrochemical oxidation of aluminum and the heat-treating of anodic aluminum oxide films are discussed.
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页码:1630 / 1635
页数:5
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