Physical Aging and Refractive Index of Poly(methyl methacrylate) Glass

被引:0
作者
Norihisa Tanio
Teruaki Nakanishi
机构
[1] Faculty of Photonics Science and Technology,
[2] Chitose Institute of Science and Technology,undefined
来源
Polymer Journal | 2006年 / 38卷
关键词
Polymer Glass; Physical Aging; Refractive Index; Prism Coupling; Volume Relaxation; Glass Transition Temperature; Poly(methyl methacrylate);
D O I
暂无
中图分类号
学科分类号
摘要
Physical aging of poly(methyl methacrylate) (PMMA) glass was studied by refractive index measurement. We measured change of refractive index of PMMA glass with annealing at temperatures below the glass transition temperature (Tg) by optical prism coupling, and determined volume relaxation by physical aging using the Lorentz-Lorenz equation. In this paper, the effect of aging temperature on volume relaxation of PMMA glass was investigated. Maximum volume relaxation for PMMA glass was determined at 18 °C below the Tg.
引用
收藏
页码:814 / 818
页数:4
相关论文
共 50 条
[21]   Effect of physical aging on the gas transport properties of poly(methyl methacrylate) membranes [J].
Hu, Chien-Chieh ;
Fu, Ywu-Jang ;
Hsiao, Sheng-Wen ;
Lee, Kueir-Rarn ;
Lai, Juin-Yih .
JOURNAL OF MEMBRANE SCIENCE, 2007, 303 (1-2) :29-36
[22]   Physical Aging of Poly(methyl methacrylate) Brushes and Spin-Coated Films [J].
Srinivasan, Sneha ;
Mcgaughey, Allyson L. ;
Ren, Zhiyong Jason ;
Zuo, Biao ;
Priestley, Rodney D. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2024, 128 (48) :11999-12007
[23]   Miscibility studies of polycarbonate/poly(methyl methacrylate) and polycarbonate/polystyrene blends as measured by viscosity, ultrasonic, and refractive index methods [J].
Rajulu, AV ;
Reddy, RL .
INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION, 2000, 5 (4-6) :467-473
[24]   Molecular Size Effects of Diarylnitrone Additive on the Refractive-Index Change in Poly(methyl methacrylate) Film [J].
Kenta Tanaka ;
Mariko Fukuda ;
Tetsutaro Igarashi ;
Tadamitsu Sakurai .
Polymer Journal, 2005, 37 :776-781
[25]   Modulation of refractive index and thickness of poly(methyl methacrylate) thin films with UV irradiation and heat treatment [J].
Yu, JM ;
Tao, XM ;
Tam, HY ;
Demokan, MS .
APPLIED SURFACE SCIENCE, 2005, 252 (05) :1283-1292
[26]   Molecular size effects of diarylnitrone additive on the refractive-index change in poly(methyl methacrylate) film [J].
Tanaka, K ;
Fukuda, M ;
Igarashi, T ;
Sakurai, T .
POLYMER JOURNAL, 2005, 37 (10) :776-781
[27]   Photoreactivity of diarylnitrone additive/pendant in poly(methyl methacrylate) film and photocontrol of refractive index for this polymer film [J].
Tanaka, K ;
Shiraishi, H ;
Takayanagi, E ;
Korechika, A ;
Igarashi, T ;
Sakurai, T .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2005, 174 (03) :199-206
[28]   Aging of a low molecular weight poly(methyl methacrylate) [J].
Casalini, R. ;
Roland, C. M. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2011, 357 (02) :282-285
[29]   Isothermal Physical Aging of Poly(methyl methacrylate)/Polyhedral Oligomeric Silsequioxanes Nanocomposite Thin Films [J].
Jin, Silro ;
Lee, Jong Keun .
APPLICATIONS OF ENGINEERING MATERIALS, PTS 1-4, 2011, 287-290 :2234-2239
[30]   Prediction of long-term physical aging of poly(methyl methacrylate) membranes for gas separation [J].
Fu, Ywu-Jang ;
Hsiao, Sheng-Wen ;
Hu, Chien-Chieh ;
Lee, Kueir-Rarn ;
Lai, Juin-Yih .
DESALINATION, 2008, 234 (1-3) :51-57