Cucurbiturils in supramolecular catalysis

被引：1
作者：
Sebastian Funk
Jürgen Schatz
机构：
[1] Friedrich-Alexander-Universität Erlangen-Nürnberg,Department of Chemistry and Pharmacy
来源：
Journal of Inclusion Phenomena and Macrocyclic Chemistry | 2020年 / 96卷
关键词：
Cucurbituril; Supramolecular chemistry; Catalysis; Molecular recognition; Macrocyclic compound; Host–guest chemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Nearly 80 years following the initial synthesis of cucurbiturils, its structure was finally revealed in 1981, which discovery opened the field for further investigation. As a result, the scope of available sizes and varieties of cucurbiturils has grown profoundly in the last four decades, leading to a large number of potential applications, including cucurbiturils in catalysis as supramolecular additives due to the capability of supramolecular binding to certain substrates. Owing to their polar portals and non-polar cavity, cucurbiturils can have an eclectic range of binding versatile guests of different shapes and electronic structures, making them especially attractive for supramolecular catalysis with a wide range of possible reaction types. This review concisely discusses the unique structure and properties of cucurbiturils, and highlights their use as molecular containers in terms of supramolecular interactions in catalytic reactions such as photoreaction, solvolysis, oxidation, metal-assisted catalysis, bromination, Diels–Alder, xanthene synthesis, and Schiff base reaction.
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页码：1 / 27
页数：26
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共 805 条
[1]  
Crini G(2014)Review: a history of cyclodextrins Chem. Rev. 114 10940-10975
[2]  
Pedersen CJ(1967)Cyclic polyethers and their complexes with metal salts J. Am. Chem. Soc. 89 7017-7036
[3]  
Cram DJ(1985)Shell closure of two cavitands forms carcerand complexes with components of the medium as permanent guests J. Am. Chem. Soc. 107 2575-2576
[4]  
Karbach S(1988)Cyclobis(paraquat-p-phenylen), ein tetrakationischer Mehrzweckrezeptor Angew. Chem. 100 1605-1608
[5]  
Kim YH(2008)para-Bridged symmetrical Pillar[5]arenes: their lewis acid catalyzed synthesis and host-guest property J. Am. Chem. Soc. 130 5022-5023
[6]  
Baczynskyj L(1981)Cucurbituril J. Am. Chem. Soc. 103 7367-7368
[7]  
Kallemeyn GW(2009)Biomimetic chemistry: biology as an inspiration J. Biol. Chem. 284 1337-1342
[8]  
Odell B(2005)Molecular structure as a blueprint for supramolecular structure chemistry in confined spaces Proc. Natl. Acad. Sci. 102 10766-10770
[9]  
Reddington MV(2005)Self-assembled nanoreactors Chem. Rev. 105 1445-1490
[10]  
Slawin AMZ(2002)Supramolecular assembly dynamics Proc. Natl. Acad. Sci. 99 4793-4796
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