Paradigms and paradoxes: patterns and estimation of the entropy of formation of some aqueous complex anions

被引：0

作者：

Maja Ponikvar

Joel F. Liebman

机构：

[1] Jožef Stefan Institute,Department of Chemistry and Biochemistry

[2] University of Maryland,undefined

来源：

Structural Chemistry | 2008年 / 19卷

关键词：

Anions; Aqueous; Enthalpy; Entropy; Gibbs energy; Patterns; Statistics;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Relationships between the entropy of formation (TΔfSo) of aqueous complex anions and simple parameters, such as negative value of the charge of the species, the number of oxygen atoms, the total number of atoms, the natural logarithm of the molecular weight, denticity, total number of anions in certain species, coordination number, and number of affixed waters were studied and discussed. Multivariate methods of analysis were used for identifying the chemometric similarities among different species.

引用

页码：501 / 508

页数：7