State of palladium in ligandless catalytic systems for the Heck reaction of nonactivated bromobenzene

被引：0
|
作者：
A. F. Schmidt
A. Al-Halaiqa
V. V. Smirnov
A. A. Kurokhtina
机构：
[1] Irkutsk State University,Faculty of Chemistry
来源：
Kinetics and Catalysis | 2008年 / 49卷
关键词：
Palladium; Catalytic System; Butyl Acrylate; Aryl Halide; Bromobenzene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In the Heck reaction of bromobenzene catalyzed by the palladium salts (PdX2) without phosphine ligands, a considerable amount of palladium (up to 70%) is not involved in the catalytic cycle and exists as the catalytically inactive anionic complex [PdX4]2−.
引用
收藏
页码：638 / 643
页数：5
相关论文
共 50 条
  • [31] A highly efficient palladium/imidazolium salt system for catalytic Heck reactions
    Yang, CL
    Nolan, SP
    SYNLETT, 2001, (10) : 1539 - 1542
  • [32] Double Mizoroki-Heck Arylation of Terminal Alkenes in the Presence of "Ligand-Free" Palladium Catalytic Systems
    Kurokhtina, A. A.
    Larina, E. V.
    Lagoda, N. A.
    Grigoryeva, T. A.
    Schmidt, A. F.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 59 (10) : 1704 - 1708
  • [33] A novel reusable polymer supported palladium catalyst for Heck reaction
    Sruthi, Pambingal Rajan
    Malini, Sivan
    Silpa, Sasi
    Anas, Saithalavi
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2025, 1025
  • [34] Synthesis, characterization of N-heterocyclic carbene metallacrown palladium complex and catalytic activities in Suzuki and Heck coupling reaction
    Wang, Jun-Wen
    Gao, Lin-Ying
    Meng, Fan-Hui
    Jiao, Jing
    Ding, Ling-Yan
    Zhang, Li-Fang
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2012, 73 (1-4) : 119 - 128
  • [35] Synthesis, characterization of N-heterocyclic carbene metallacrown palladium complex and catalytic activities in Suzuki and Heck coupling reaction
    Jun-Wen Wang
    Lin-Ying Gao
    Fan-Hui Meng
    Jing Jiao
    Ling-Yan Ding
    Li-Fang Zhang
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2012, 73 : 119 - 128
  • [36] PALLADIUM BASED MULTICOMPONENT CATALYTIC-SYSTEMS FOR THE ALCOHOL TO CARBOXYLATE OXIDATION REACTION
    KIMURA, H
    KIMURA, A
    KOKUBO, I
    WAKISAKA, T
    MITSUDA, Y
    APPLIED CATALYSIS A-GENERAL, 1993, 95 (02) : 143 - 169
  • [37] Palladium Supported on SBA-15 as a New Recyclable Catalyst for the Mizoroki-Heck Reaction
    Zhang Feibao
    Zhang Caihua
    Deng Yuan
    Xu Liwen
    Qiu Huayu
    Lai Guoqiao
    Jiang Jianxiong
    ACTA CHIMICA SINICA, 2010, 68 (05) : 443 - 448
  • [38] Enantioselective Intramolecular Reductive Heck Reaction with a Palladium/Monodentate Phosphoramidite Catalyst
    Mannathan, Subramaniyan
    Raoufmoghaddam, Saeed
    Reek, Joost N. H.
    de Vries, Johannes G.
    Minnaard, Adriaan J.
    CHEMCATCHEM, 2017, 9 (04) : 551 - 554
  • [39] Oxidative Heck Reaction of Fluorinated Olefins with Arylboronic Acids by Palladium Catalysis
    Li, Yang
    Tu, Dong-Huai
    Gu, Yu-Jie
    Wang, Bo
    Wang, Yao-Yu
    Liu, Zhao-Tie
    Liu, Zhong-Wen
    Lu, Jian
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2015, 2015 (20) : 4340 - 4343
  • [40] Density functional study of the complete pathway for the Heck reaction with palladium diphosphines
    Surawatanawong, Panida
    Fan, Yubo
    Hall, Michael B.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (8-9) : 1552 - 1563
12345