State of palladium in ligandless catalytic systems for the Heck reaction of nonactivated bromobenzene

被引：0
|
作者：
A. F. Schmidt
A. Al-Halaiqa
V. V. Smirnov
A. A. Kurokhtina
机构：
[1] Irkutsk State University,Faculty of Chemistry
来源：
Kinetics and Catalysis | 2008年 / 49卷
关键词：
Palladium; Catalytic System; Butyl Acrylate; Aryl Halide; Bromobenzene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In the Heck reaction of bromobenzene catalyzed by the palladium salts (PdX2) without phosphine ligands, a considerable amount of palladium (up to 70%) is not involved in the catalytic cycle and exists as the catalytically inactive anionic complex [PdX4]2−.
引用
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页码：638 / 643
页数：5
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