Vinyl-gem-dichlorocyclopanes in radical polymerization

被引：0
作者：
S. V. Kolesov
A. I. Vorob’ev
S. S. Zlotskii
A. P. Khamidullina
E. A. Brusentsova
R. R. Muslukhov
L. V. Spirikhin
G. E. Zaikov
机构：
[1] Russian Academy of Sciences,Institute of Organic Chemistry, Ufa Scientific Center
[2] Ufa State Oil Technical University,Emmanuel Institute of Biochemical Physics
[3] Russian Academy of Sciences,undefined
来源：
Russian Journal of General Chemistry | 2008年 / 78卷
关键词：
Copolymerization; General Chemistry; Cyclopropane; Radical Polymerization; Methyl Methacrylate;
D O I：
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中图分类号：
学科分类号：
摘要：
Vinyl-gem-dichlorocyclopropanes in the presence of radical type initiators undergo isomerizational homo-and copolymerization with vinyl monomers to form copolymers with the random distribution of monomer units in the macrochain. As compared to vinyl monomers like methyl methacrylate, acrylonitrile, and styrene they are considerably less active. By means of 13C NMR spectroscopy it was shown that vinyl-gem-dichlorocyclopropanes polymerized forming steroblock polymers of mainly trans-structure.
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页码：925 / 928
页数：3
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