Synthesis of a ternary Ag/RGO/ZnO nanocomposite via microwave irradiation and its application for the degradation of Rhodamine B under visible light

被引:0
作者
Divya Kollikkara Surendran
Marilyn Mary Xavier
Vandana Parakkal Viswanathan
Suresh Mathew
机构
[1] Mahatma Gandhi University,School of Chemical Sciences
[2] Mahatma Gandhi University,Advanced Molecular Materials Research Centre
来源
Environmental Science and Pollution Research | 2017年 / 24卷
关键词
Rhodamine B; Visible light; Photocatalysis; Microwave irradiation; Plasmonic photocatalyst;
D O I
暂无
中图分类号
学科分类号
摘要
Reduced graphene oxide supporting plasmonic photocatalyst (Ag) on ZnO has been synthesized via a facile two-step microwave synthesis using RGO/ZnO and AgNO3. First step involves fabrication of RGO/ZnO via microwave irradiation. The nanocomposites were characterized by X-ray diffraction analysis, transmission electron microscopy, Fourier transform infrared spectroscopy, and Raman spectroscopy. Ag/RGO/ZnO shows enhanced photoactivity under visible light for the degradation of Rhodamine B. Enhanced charge separation and migration have been assigned using UV-vis diffuse reflectance spectra, photoluminescence spectra, electrochemical impedance spectra, and TCSPC analysis. The improved photoactivity of Ag/RGO/ZnO can be ascribed to the prolonged lifetime of photogenerated electron–hole pairs and effective interfacial hybridization between RGO and Ag with ZnO nanoparticles. Ag nanoparticles can absorb visible light via surface plasmon resonance to enhance photocatalytic activity.
引用
收藏
页码:15360 / 15368
页数:8
相关论文
共 154 条
  • [21] Linic S(2011)Facile synthesis and enhanced photocatalytic performance of flower-like ZnO hierarchical microstructures Sci Adv Mater 3 59-65
  • [22] Cong H-P(2013)Plasmon resonant enhancement of photocatalytic water splitting under visible illumination Adv Funct Mater 23 1743-1749
  • [23] Ren X-C(2011)Nanophotocatalysts via microwave-assisted solution-phase synthesis for efficient photocatalysis J Colloid Interface Sci 363 521-528
  • [24] Wang P(2010)Removal of dyes from the effluent of textile and dyestuff manufacturing industry: a review of emerging techniques with reference to biological treatment New J Chem 34 1094-1096
  • [25] Yu S-H(2010)Gold loaded Titania nanostructures—synthesis, characterization and morphology dependence on Photocatalysis Chem Commun 46 5250-5252
  • [26] Dou P(2015)Synthesis of Ag doped nano TiO2 as efficient solar photocatalyst for the degradation of endosulfan Phys Chem Chem Phys 17 18645-18652
  • [27] Tan F(2006)Enhancement of sunlight photocatalysis of nano TiO Chem Rev 106 4301-4320
  • [28] Wang W(2014) by Ag nanoparticles stabilized with D-glucosamine J Mater Chem A 2 9380-9389
  • [29] Sarreshteh A(2012)An in situ simultaneous reduction-hydrolysis technique for fabrication of TiO2-graphene 2D sandwich-like hybrid Nanosheets: graphene-promoted selectivity of photocatalytic-driven hydrogenation and coupling of CO2 into methane and ethane Chem Soc Rev 41 782-796
  • [30] Qiao X(2011)Large-scale synthesis of ZnO balls made of fluffy thin nanosheets by simple solution process: structural, optical and photocatalytic properties Appl Catal B Environ 101 382-387