Investigation of imidazole derivatives as corrosion inhibitors for mild steel in sulfuric acidic environment: experimental and theoretical studies

被引：0
作者：
M. Ouakki
M. Galai
M. Rbaa
Ashraf S. Abousalem
B. Lakhrissi
E. H. Rifi
M. Cherkaoui
机构：
[1] Laboratory of Materials,Department of Chemistry, Faculty of Science
[2] Electrochemistry and Environment (LMEE),Quality Control LaboratoryOperations Department
[3] Laboratory of Materials Engineering and Environment: Modelling and Application (LMEEMA),National Higher School of Chemistry (NHSC)
[4] Laboratory of Organic Chemistry,undefined
[5] Catalysis and Environment,undefined
[6] Mansoura University,undefined
[7] Jotun Egypt,undefined
[8] Laboratory of Organic Synthesis and Extraction Processes (LOSEP),undefined
[9] University Ibn Tofail,undefined
来源：
Ionics | 2020年 / 26卷
关键词：
Imidazole derivatives; Corrosion inhibition; SEM-EDAX; DFT; Molecular dynamic;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In this work, we are interested in studying the effect of the addition of three heterocyclic organic compound derived from imidazole, namely 2-(1,4,5-triphenyl-1H-imidazol-2-yl)phenol (IM-OH), 1,4,5-triphenyl-2-(4-metyoxyphenyl)-1H-imidazole (IM-OCH3), and 3-methoxy-4-(1,4,5-triphenyl-1H-imidazol-2-yl)phenol (IM-H) on the corrosion inhibition of mild steel in acidic medium H2SO4 0.5 M. This study was performed using weight loss and electrochemical and theoretical investigations. The obtained results indicate that IM-OH, IM-OCH3, and IM-H act as excellent inhibitors for mild steel in H2SO4 0.5 M. The results obtained from the electrochemical methods show that IM-OH, IM-OCH3, and IM-H imparted high resistance and behave as mixed type inhibitors. Inhibition efficiency (IE %) increases with the increase of inhibitors concentration to attain 97.7%, 98.9%, and 88.9% at 10−3 M of IM-OH, IM-OCH3, and IM-H respectively. EIS data is analyzed to model the inhibition process through appropriate equivalent circuit model. Thermodynamic and kinetic parameters controlling the adsorption process are calculated and discussed. In addition, the surface of the mild steel has been analyzed by the SEM-EDAX. The theoretical results were in good agreement with experimental measurements.
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页码：5251 / 5272
页数：21
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共 338 条
[1]  
Rbaa M(2018)Synthesis and investigation of quinazoline derivatives based on 8-hydroxyquinoline as corrosion inhibitors for mild steel in acidic environment: experimental and theoretical studies Ionics 2 1-19
[2]  
Galai M(2011)Corrosion inhibition studies of mild steel by new inhibitor in different corrosive medium Res J Chem Sci 1 46-50
[3]  
Benhiba F(2005)The inhibitive effect of bipyrazolic derivatives on the corrosion of steel in hydrochloric acid solution Appl Surf Sci 252 1378-1385
[4]  
Obot IB(2019)Experimental, quantum chemical and molecular dynamic studies on the action of arylthiophene derivatives as acid corrosion inhibitors J Mol Liq 290 111178-665
[5]  
Oudda H(2014)An investigation on the inhibitory action of benzazole derivatives as a consequence of sulfur atom induction Appl Surf Sci 317 657-3106
[6]  
EbnTouhami M(2012)Cantellaasiatica extracts as green corrosion inhibitors for mild steel in 0.5 M H Adv Appl Sci Res 3 3097-416
[7]  
Zarrouk A(2017)SO Portugaliae Electrochimica Acta 35 233-204
[8]  
Shylesh BS(1995)L-methionine methyl ester hydrochloride as a corrosion inhibitor of iron in acid chloride solution Corrosion 51 411-200
[9]  
Ventkatesh TV(2002)New bipyrazole derivatives as effective inhibitors for the corrosion of mild steel in 1M HCI medium Anti-Corros Meth Mater 49 199-249
[10]  
Praveen BM(2000)Étude électrochimique de l'inhibition de la corrosion de l'alliage d'aluminium 3003 en milieu bicarbonate par les composés triazolique Ann Chim Sci Mater 25 187-230
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