Ionic conductivity of potassium antimonate tungstates with partial Na+ or Li+ substitution for K+

被引：0
|
作者：
Yu. A. Lupitskaya
V. A. Burmistrov
机构：
[1] Chelyabinsk State University,
来源：
Inorganic Materials | 2013年 / 49卷
关键词：
Unit Cell Parameter; Pyrochlore Phase; Pyrochlore Structure; Anti Mony Oxide; Composition Triangle;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
We have studied the formation of monovalent metal antimonate tungstates by solid-state reactions in the xM2CO3 · (y − x)K2CO3 · ySb2O3 · 2(2 − y)WO3 (M = Na, Li; 0 ≤ x ≤ y; 1.0 ≤ y ≤ 2.0) systems and identified the stability regions of pyrochlore phases at a temperature of 1123 K in the KSbO3-WO3-MSbO3 (M = Na, Li) composition triangles. A model has been proposed for the ion distribution over the sites of the pyrochlore structure (sp. gr. Fd3m). The conductivity of the monovalent metal antimonate tungstates has been measured in the temperature range 500–1000 K, and a relationship between their ionic conductivity and structure has been established.
引用
收藏
页码：930 / 934
页数：4
相关论文
共 50 条
  • [31] DFT study of the cryptand and benzocryptand and their complexes with alkali metal cations:: Li+, Na+, K+
    Wang, Xueye
    Wang, Hengliang
    Tan, Yuanqiang
    JOURNAL OF COMPUTATIONAL CHEMISTRY, 2008, 29 (09) : 1423 - 1428
  • [32] STUDIES ON PRIMARY HYDRATED COMPLEXES OF LI+, NA+ AND K+ IONS BY EXTENDED HUCKEL METHOD
    ZHOGOLEV, DA
    BUNYATYA.BK
    KRUGLYAK, YA
    CHEMICAL PHYSICS LETTERS, 1973, 18 (01) : 135 - 139
  • [33] Li+, Na+, K+ and Be2+ bonds -: IR continua and cation polarizabilities of these bonds
    Zundel, G
    JOURNAL OF MOLECULAR STRUCTURE, 1999, 511 : 19 - 33
  • [34] PRINCIPLES OF LI+, NA+ AND K+ CATION SORPTION BY MIXED TITANIUM AND ZIRCONIUM-PHOSPHATES
    BUDOVITSKAYA, TA
    VOITKO, II
    BORTUN, AI
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1992, 35 (01): : 46 - 49
  • [35] THE MOBILITY OF NA+, LI+, AND K+ IONS IN THERMALLY GROWN SIO2-FILMS
    GREEUW, G
    VERWEY, JF
    JOURNAL OF APPLIED PHYSICS, 1984, 56 (08) : 2218 - 2224
  • [36] Vibrational analysis of complexes of urate with IA group metal cations (Li+, Na+ and K+)
    Allen, Reeshemah N.
    Lipkowski, Pawel
    Shukla, M. K.
    Leszczynski, Jerzy
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2007, 68 (03) : 639 - 645
  • [37] PHASE-DIAGRAM OF LI+, NA+, K+, RB+ IBR- SYSTEM
    CHERNOV, RV
    BUGAENKO, VV
    ZHURNAL NEORGANICHESKOI KHIMII, 1973, 18 (11): : 3096 - 3101
  • [38] IONIC-CONDUCTIVITY IN NA+, K+, AND AG+ BETA-''-ALUMINA
    BRIANT, JL
    FARRINGTON, GC
    JOURNAL OF SOLID STATE CHEMISTRY, 1980, 33 (03) : 385 - 390
  • [39] Improving ionic conductivity by Mg-doping of A2SnO3 (A = Li+, Na+)
    Blazquez-Alcover, I.
    Rousse, G.
    Corte, D. Alves Dalla
    Badot, J. C.
    Grimaud, A.
    Rozier, P.
    Tarascon, J. M.
    SOLID STATE IONICS, 2017, 308 : 16 - 21
  • [40] STANDARD ELECTRODE-POTENTIALS OF LI/LI+, NA/NA+, AND K/K+ IN PROPYLENE CARBONATE AND ITS MIXTURE WITH DIMETHYL-SULFOXIDE FROM FREE-ENERGIES OF IONIC SOLVATION
    BASUMALLICK, SR
    BASUMALLICK, IN
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (12) : 3876 - 3878
12345