Oxidative desulfurization of hydrocarbon fuel with high olefin content

被引：0
作者：
A. V. Akopyan
E. V. Ivanov
P. D. Polikarpova
A. V. Tarakanova
E. V. Rakhmanov
O. V. Polyakova
A. V. Anisimov
V. A. Vinokurov
E. A. Karakhanov
机构：
[1] Moscow State University,Faculty of Chemistry
来源：
Petroleum Chemistry | 2015年 / 55卷
关键词：
desulfurization; hydrogen peroxide; fuel; catalytic cracking; peroxo complexes; transition metals;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The influence of olefins on the oxidative desulfurization of model mixtures and catalytically cracked gasoline has been studied. It has been established using model mixtures and a wide-cut fraction of catalytically cracked gasoline that the presence of olefins in fuel suppresses the oxidative desulfurization process as a result of occurrence of side oxidation reactions of unsaturated compounds. It has been shown that under the given conditions, it is preferable to use neutral catalysts based on transition metal salts for the oxidative desulfurization, rather than catalysts of acidic nature.
引用
收藏
页码：571 / 574
页数：3
相关论文
共 33 条
[1]  
Aladysheva E. Z.(1988)undefined Khim. Tekhnol. Topl. Masel 3 34-undefined
[2]  
Matsuzawa S.(2002)undefined J. Photochem. Photobiol., A 149 183-undefined
[3]  
Tanaka J.(2007)undefined Appl. Catal., A 319 237-undefined
[4]  
Sato S.(2004)undefined Chem. Lett. 33 1306-undefined
[5]  
Takashi I.(2009)undefined Khim. Tekhnol. 10 388-undefined
[6]  
Wan M.(2003)undefined Catal. Today 78 319-undefined
[7]  
Yen T.(2007)undefined Appl. Catal. B: Environ. 73 311-undefined
[8]  
Yazu K.(1997)undefined J. Mol. Catal. A: Chem. 117 397-undefined
[9]  
Makino M.(2003)undefined Appl. Catal. A 253 91-undefined
[10]  
Ukegawa K.(2008)undefined Appl. Catal. A: Gen. 334 366-undefined
1234