Calculating the molecular constants for the B1Πu, C1Πu, (1)1Πg, and (2) Σg+ electronic states of the rubidium dimer

被引：0
作者：
A. D. Smirnov
机构：
[1] Bauman State Technical University,
来源：
Russian Journal of Physical Chemistry A | 2011年 / 85卷
关键词：
rubidium dimer; electronic states; vibrational; rotational; and centrifugal constants;
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学科分类号：
摘要：
The vibrational, rotational, and centrifugal constants are calculated for the B1Πu, C1Πu, (1) 1Πg, and (2) electronic states of a 85Rb2 molecule. The calculations are based on the semi-empirical potential curves obtained in this work. The results from calculating the molecular constants are compared with experimental data. The Franck-Condon factors and Rv′v″ centroids are calculated for the electronic transitions B1Πu-X1Σg+, C1Πu-X1Σg+, C1Πu-(1) 1Πg, and C1Πu-(2) 1Σg+.
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页码：1026 / 1030
页数：4
相关论文
共 33 条
[1]  
Johnson D. E.(1985)undefined J. Opt. Soc. Am. 2 721-undefined
[2]  
Eden I. G.(1991)undefined Opt. Spektrosk. 71 29-undefined
[3]  
Vetchinkin S. I.(1996)undefined Opt. Spektrosk. 81 390-undefined
[4]  
Umanskii I. M.(2002)undefined Zh. Fiz. Khim. 76 284-undefined
[5]  
Smirnov A. D.(2003)undefined Zh. Fiz. Khim. 77 478-undefined
[6]  
Smirnov A. D.(2003)undefined Zh. Strukt. Khim. 44 828-undefined
[7]  
Smirnov A. D.(2007)undefined Zh. Strukt. Khim. 48 27-undefined
[8]  
Smirnov A. D.(2002)undefined Opt. Spektrosk. 93 739-undefined
[9]  
Smirnov A. D.(2007)undefined Opt. Spektrosk. 102 33-undefined
[10]  
Smirnov A. D.(1980)undefined Chem. Phys. 54 21-undefined
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