Reactions of N,N-dihexyloctanamide with nitrate and dodecane radicals: a pulse radiolysis study

被引：0
作者：
Ravi Joshi
P. N. Pathak
V. K. Manchanda
S. K. Sarkar
T. Mukherjee
机构：
[1] Bhabha Atomic Research Center,Radiation & Photochemistry Division
[2] Bhabha Atomic Research Center,Radiochemistry Division
[3] Bhabha Atomic Research Center,Chemistry Group
来源：
Research on Chemical Intermediates | 2010年 / 36卷
关键词：
DHOA; Extractant; Pulse radiolysis; Transients; Kinetics;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Recently, completely incinerable N,N-dihexyloctanamide (DHOA) has been identified as a promising alternative to tri-n-butyl phosphate for the reprocessing of spent nuclear fuels. The present work deals with the pulsed radiolytic investigation on the reactions of DHOA with the radicals produced in the radiolysis of nitric acid and dodecane medium. The rate constants of the reactions of DHOA with solvated electron, nitrate radical and dodecane radicals have been measured and the transients have been characterized. In addition, the reactions of DHOA transients have also been studied.
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页码：503 / 510
页数：7
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