Zeolite catalysts modified with zirconium and sulfur compounds in the conversion of dimethyl ether to lower olefins

被引:0
作者
N. V. Kolesnichenko
E. E. Kolesnikova
L. E. Kitaev
E. N. Biryukova
N. I. Trukhmanova
S. N. Khadzhiev
机构
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
来源
Petroleum Chemistry | 2012年 / 52卷
关键词
Zirconium; Zeolite; Petroleum Chemistry; Zeolite Catalyst; Lower Olefin;
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暂无
中图分类号
学科分类号
摘要
The effect of zirconium addition to zeolite-containing catalysts for dimethyl ether conversion to lower olefins has been studied. The effect of the nature of the zirconium compound on the catalytic properties of a zeolite catalyst has been analyzed, and a method for generating new acid sites through the sulfation of a Zr-containing zeolite matrix has been developed. Using physicochemical methods, it has been shown that the processing of a zeolite with zirconium and sulfur compounds does not lead to the degradation of its structure and a change in the adsorption volume.
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页码:155 / 160
页数:5
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